Sylabus przedmiotu
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Przedmiot: | Adsorbents and catalysts | ||||||||||||
Kierunek: | Chemia, II stopień [4 sem], stacjonarny, ogólnoakademicki, rozpoczęty w: 2014 | ||||||||||||
Specjalność: | materials chemistry | ||||||||||||
Rok/Semestr: | I/1 | ||||||||||||
Liczba godzin: | 30,0 | ||||||||||||
Nauczyciel: | Ryczkowski Janusz, dr hab. | ||||||||||||
Forma zajęć: | wykład | ||||||||||||
Rodzaj zaliczenia: | egzamin | ||||||||||||
Punkty ECTS: | 4,0 | ||||||||||||
Godzinowe ekwiwalenty punktów ECTS (łączna liczba godzin w semestrze): |
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Poziom trudności: | zaawansowany | ||||||||||||
Wstępne wymagania: | Fundamentals of physical chemistry, chemical technology and base knowledgeof spectroscopic methods. |
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Metody dydaktyczne: |
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Zakres tematów: | Definition of the adsorption, the thermodynamical description , free energy at the interfaces (Gibbs equation). Adsorption isotherms for the gas-phase; determination and the Langmuir model. Theory and BET equation. The potential of the adsorption. Adsorption from solutions. Kinds of adsorbents and their physicochemical characterization (with the regard of spectroscopic methods). The catalysis and catalysts. Models of the reacting molecules. The energy-part of the third body in chemical reactions. The formal kinetics of heterogeneous catalytic reactions – mono- and bimolecular reactions. Mechanisms of the catalytic bimolecular reactions. Stages limiting rate of the catalytic reactions. Experimental kinetic equations of the catalytic reactions. Active centers on the catalysts’ surface and catalytic activity. Geometrical, energetic and electronic aspects of the heterogeneous catalysis phenomena. The classification of heterogeneous catalysts and the characterization of main catalysts groups. Preparation of heterogeneous catalysts - basic stages, methods of preparation, unit and process operations for catalysts precursors transformation into the final form (drying, calcination, reduction). The modern approach for catalysts design. |
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Forma oceniania: |
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Warunki zaliczenia: | credits and final exam |
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Literatura: | 1. M. Bowker, The basis and application of heterogeneous catalysis, Oxford Univ. Press, 1998. 2. J.M. Thomas, W.J. Thomas, Principles and practice of heterogeneous catalysis, VCH Weinheim, 1996. 3. G.C. Bond, Heterogeneous catalysis (2nd edition), Oxford Univ. Press, 1987. 4. J.M. Campbell, Catalysis at Surfaces, Chapman and Hall, London 1988. |
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Modułowe efekty kształcenia: |
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